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Xanthic Acid

1911 Encyclopedia Britannica

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XANTHIC ACID (xanthogenic acid), C H O

CS. SH, an organic acid named from the Greek avOos, yellow, in allusion to the bright yellow colour of its copper salt. The salts of this acid are formed by the action of carbon bisulphide on the alcoholates, or on alcoholic solutions of the caustic alkalis. They react with the alkyl iodides to form dialkyl esters of the dithio-carbonic acid, which readily decompose into mercaptans and thiocarbamic esters on treatment with ammonia: C H O

CS

SR +NH =C H O

CS

NH +R

SH; with the alkali alcoholates they give salts of the alkyl thiocarbonic acids: C H O

CS

SR +CH30K+H20=CH30

CO

SK+C2H50H+R

SH. Ethyl xanthic acid, C H O

Cssh, is obtained by the action of dilute sulphuric acid on the potassium salt at o° C. (Zeise, Berz. Jahresb., 3, p. 83). It is a colourless oil which is very unstable, decomposing at 25° C. into carbon bisulphide and alcohol. The potassium salt crystallizes in colourless needles and is formed by shaking carbon bisulphide with a solution of caustic potash in absolute alcohol. On the addition of cupric sulphate to its aqueous solution it yields a yellow precipitate of cupric xanthate. Potassium xanthate is used in indigo printing and also as an antidote for phylloxera. Tschugaeff ( Ber., 18 99, 3 2, p. 333 2) has used the xanthic ester formation for the preparation of various terpenes, the methyl ester whet distilled under slightly diminished pressure decomposing, in the sense of the equation, C2,H27,_1.O.CS

SCH3= C, H n_ +COS+CH SH. According to the author molecular change in the hydrocarbon is prevented, since no acid agent is used.