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Light
1911 Encyclopedia Britannica
'LIGHT.' Introduction. - § 1. " Light " may be defined subjectively as the sense-impression formed by the eye. This is the most familiar connotation of the term, and suffices for the discussion of optical subjects which do not require an objective definition, and, in particular, for the treatment of physiological optics and vision. The objective definition, or the " nature of light," is the ultima Thule of optical research. " Emission theories," based on the supposition that light was a stream of corpuscles, were at first accepted. These gave place during the opening decades of the 19th century to the "undulatory or wave theory," which may be regarded as culminating in the " elastic solid theory " - so named from the lines along which the mathematical investigation proceeded - and according to which light is a transverse vibratory motion propagated longitudinally though the aether. The mathematical researches of James Clerk Maxwell have led to the rejection of this theory, and it is now held that light is identical with electromagnetic disturbances, such as are generated by oscillating electric currents or moving magnets. Beyond this point we cannot go at present. To quote Arthur Schuster (Theory of Optics, 1904), "So long as the character of the displacements which constitute the waves remains undefined we cannot pretend to have established a theory of light." It will thus be seen that optical and electrical phenomena are co-ordinated as a phase of the physics of the " aether," and that the investigation of these sciences culminates in the derivation of the properties of this conceptual medium, the existence of which was called into being as an instrument of research.' The methods of the elastic-solid theory can still be used with advantage in treating many optical phenomena, more especially so long as we remain ignorant of fundamental matters concerning the origin of electric and magnetic strains and stresses; in addition, the treatment is more intelligible, the researches on the electromagnetic theory leading in many cases to the derivation of differential equations which express quantitative relations between diverse phenomena, although no precise meaning can be attached to the symbols employed. The school following Clerk Maxwell and Heinrich Hertz has certainly laid the foundations of a complete theory of light and electricity, but the methods must be adopted with caution, lest one be constrained to say with Ludwig Boltzmann as in the introduction to his Vorlesungen fiber Maxwell's Theorie der Elektricitlit and des Lichtes:- " So soil ich denn mit saurem Schweiss Euch lehren, was ich selbst nicht weiss." Goethe, Faust. The essential distinctions between optical and electromagnetic phenomena may be traced to differences in the lengths of lightwaves and of electromagnetic waves. The aether can probably transmit waves of any wave-length, the velocity of longitudinal propagation being about 3.10 10 cms. per second. The shortest waves, discovered by Schumann and accurately measured by Lyman, have a wave-length of o0001 mm.; the ultra-violet, recognized by their action on the photographic plate or by their promoting fluorescence, have a wave-length of 00002 mm.; the eye recognizes vibrations of a wave-length ranging from about 0.0004 mm. (violet) to about 0.0007 (red); the infra-red rays, recognized by their heating power or by their action on phosphorescent bodies, have a wave-length of oooi mm.; and the longest waves present in the radiations of a luminous source are the residual rays (" Rest-strahlen ") obtained by repeated reflections from quartz (. 0085 mm.), from fluorite (0.056 mm.), and from sylvite (o06 mm.). The research-field of optics includes the investigation of the rays which we have just enumerated. A delimitation may then be made, inasmuch as luminous sources yield no other radiations, and also since the next series of waves, the electromagnetic waves, have a minimum wave-length of 6 mm.
§ 2. The commonest subjective phenomena of light are colour and visibility, experiments of Young, Fresnel, Lloyd, Fizeau and Foucault, of Fresnel and Arago on the measurement of refractive indices by the shift of the interference bands, of H. F. Talbot on the t " Talbot bands " (which he insufficiently explained on the principle of interference, it being shown by Sir G. B. Airy that diffraction phenomena supervene), of Baden-Powell on the " Powell bands," of David Brewster on " Brewster's bands," have been developed, together with many other phenomena - Newton's rings, the colours of thin, thick and mixed plates, &c. - in a striking manner, one of the most important results being the construction of interferometers applicable to the determination of refractive indices and wave-lengths, with which the names of Jamin, Michelson, Fabry and Perot, and of Lummer and E. Gehrcke are chiefly associated. The mathematical investigations of Fresnel may be regarded as being completed by the analysis chiefly due to Airy, Stokes and Lord Rayleigh. Mention may be made of Sir G. G. Stokes' attribution of the colours of iridescent crystals to periodic twinning; this view has been confirmed by Lord Rayleigh (Phil. Mag., 1888) who, from the purity of the reflected light, concluded that the laminae were equidistant by the order of a wave-length. Prior to 1891 only interference between waves proceeding in the same direction had been studied. In that year Otto H. Wiener obtained, on a film 2 o th of a wave-length in thickness, photographic impressions of the stationary waves formed by the interference of waves proceeding in opposite directions, and in 1892 Drude and Nernst employed a fluorescent film to record the same phenomenon. This principle is applied in the Lippmann colour photography, which was suggested by W. Zenker, realized by Gabriel Lippmann, and further investigated by R. G. Neuhauss, O. H. Wiener, H. Lehmann and others.
Great progress has been made in the study of diffraction, and " this department of optics is precisely the one in which the wave theory has secured its greatest triumphs " (Lord Rayleigh). The mathematical investigations of Fresnel and Poisson were placed on a dynamical basis by Sir G. G. Stokes; and the results gained more ready interpretation by the introduction of " Babinet's principle " in 1837, and Cornu's graphic methods in 1874. The theory also gained by the researches of Fraunhofer, Airy, Schwerd, E. Lommel and others. The theory of the concave grating, which resulted from H. A. Rowland's classical methods of ruling lines of the necessary nature and number on curved surfaces, was worked out by Rowland, E. Mascart, C. Runge and others. The resolving power and the intensity of the spectra have been treated by Lord Rayleigh and Arthur Schuster, and more recently (1905), the distribution of light has been treated by A. B. Porter. The theory of diffraction is of great importance in designing optical instruments, the theory of which has been more especially treated by Ernst Abbe (whose theory of microscopic vision dates from about 1870) by the scientific staff at the Zeiss works, Jena, by Rayleigh and others. The theory of coronae (as diffraction phenomena) was originally due to Young, who, from the principle involved, devised the eriometer for measuring the diameters of very small objects; and Sir G. G. Stokes subsequently explained the appearances presented by minute opaque particles borne on a transparent plate. The polarization of the light diffracted at a ° slit was noted in 1861 by Fizeau, whose researches were extended in 1892 by H. Du Bois, and, for the case of gratings, by Du Bois and Rubens in 1904. The diffraction of light by small particles was studied in the form of very fine chemical precipitates by John Tyndall, who noticed the polarization of the beautiful cerulean blue which was transmitted. This subject - one form of which is presented in the blue colour of the sky - has been most auspiciously treated by Lord Rayleigh on both the elasticsolid and electromagnetic theories. Mention may be made of R. W. Wood's experiments on thin metal films which, under certain conditions, originate colour phenomena inexplicable by interference and diffraction. These colours have been assigned to the principle of optical resonance, and have been treated by Kossonogov (Phys. Zeit., 1903). J. C. Maxwell Garnett (Phil. Trans. vol. 203) has shown that the colours of coloured glasses are due to ultra-microscopic particles, which have been directly studied by H. Siedentopf and R. Zsigmondy under limiting oblique illumination.
Polarization phenomena may, with great justification, be regarded as the most engrossing subject of optical research during the 19th century; the assiduity with which it was cultivated in the opening decades of that century received a great stimulus when James Nicol devised in 1828 the famous " Nicol prism," which greatly facilitated the determination of the plane of vibration of polarized light, and the facts that light is polarized by reflection, repeated refractions, double refraction and by diffraction also contributed to the interest which the subject excited. The rotation of the plane of polarization by quartz was discovered in 1811 by Arago; if white light be used the colours change as the Nicol rotates - a phenomenon termed by Biot " rotatory dispersion." Fresnel regarded rotatory polarization as compounded from rightand lef t-handed (dextroand laevo-) circular polarizations; and Fresnel, Cornu, Dove and Cotton effected their experimental separation. Legrand des Cloizeaux discovered the enormously enhanced rotatory polarization of cinnabar, a property also possessed - but in a lesser degree - by the sulphates of strychnine and ethylene diamine. The rotatory power of certain liquids was discovered by Biot in 1815; and at a later date it was found that many solutions behaved similarly. A. Schuster distinguishes substances with regard to their action on polarized light as follows: substances which act in the isotropic state are termed photogyric; if the rotation be associated with crystal structure, crystallogyric; if the rotation be due to a magnetic field, magnetogyric; for cases not hitherto included the term allogyric is employed, while optically inactive substances are called isogyric. The theory of photogyric and crystallogyric rotation has been worked out on the elastic-solid (MacCullagh and others) and on the electromagnetic hypotheses (P. Drude, Cotton, &c.). Allogyrism is due to a symmetry of the molecule, and is a subject of the greatest importance in modern (and, more especially, organic) chemistry (see Stereoisomerism).
The optical properties of metals have been the subject of much experimental and theoretical inquiry. The explanations of MacCullagh and Cauchy were followed by those of Beer, Eisenlohr, Lundquist, Ketteler and others; the refractive indices were determined both directly (by Kundt) and indirectly by means of Brewster's law; and the reflecting powers from X = 251 µµ to X = 1500 µµ were determined in1900-1902by Rubens and Hagen. The correlation of the optical and electrical constants of many metals has been especially studied by P. Drude (1900) and by Rubens and Hagen (1903).
The transformations of luminous radiations have also been studied. John Tyndall discovered calorescence. Fluorescence was treated by John Herschel in 1845, and by David Brewster in 1846, the theory being due to Sir G. G. Stokes (1852). More recent studies have been made by Lommel, E. L. Nichols and Merritt (Phys. Rev., 1904), and by Millikan who discovered polarized fluorescence in 1895. Our knowledge of phosphorescence was greatly improved by Becquerel, and Sir James Dewar obtained interesting results in the course of his low temperature researches (see Liquid Gases). In the theoretical and experimental study of radiation enormous progress has been recorded. The pressure of radiation, the necessity of which was demonstrated by Clerk Maxwell on the electromagnetic theory, and, in a simpler manner, by Joseph Larmor in his article Radiation in these volumes, has been experimentally determined by E. F. Nichols and Hull, and the tangential component by J. H. Poynting. With the theoretical and practical investigation the names of Balfour Stewart, Kirchhoff, Stefan, Bartoli, Boltzmann, W. Wien and Larmor are chiefly associated. Magneto-optics, too, has been greatly developed since Faraday's discovery of the rotation of the plane of polarization by the magnetic field. The rotation for many substances was measured by Sir William H. Perkin, who attempted a correlation between rotation and composition. Brace effected the analysis of the beam into its two circularly polarized components, and in 1904 Mills measured their velocities. The Kerr effect, discovered in 1877, and the Zeeman effect (1896) widened the field of research, which, from its intimate connexion with the nature of light and electromagnetics, has resulted in discoveries of the greatest importance.
§ 14. Optical Instruments. - Important developments have been made in the construction and applications of optical instruments. To these three factors have contributed. The mathematician has quantitatively analysed the phenomena observed by the physicist, and has inductively shown what results are to be expected from certain optical systems. A consequence of this was the detailed study, and also the preparation, of glasses of diverse properties; to this the chemist largely contributed, and the manufacture of the so-called optical glass (see Glass) is possibly the most scientific department of glass manufacture. 'The mathematical investigations of lenses owe much to Gauss, Helmholtz and others, but far more to Abbe, who introduced the method of studying the aberrations separately, and applied his results with conspicuous skill to the construction of optical systems. The development of Abbe's methods constitutes the main subject of research of the presentday optician, and has brought about the production of telescopes, microscopes, photographic lenses and other optical apparatus to an unprecedented pitch of excellence. Great improvements have been effected in the stereoscope. Binocular instruments with enhanced stereoscopic vision, an effect achieved by increasing the distance between the object glasses, have been introduced. In the study of diffraction phenomena, which led to the technical preparation of gratings, the early attempts of Fraunhofer, Nobert and Lewis Morris Rutherfurd, were followed by H. A. Rowland's ruling of plane and concave gratings which revolutionized spectroscopic research, and, in 1898, by Michelson's invention of the echelon grating. Of great importance are interferometers, which permit extremely accurate determinations of refractive indices and wave-lengths, and Michelson, from his classical evaluation of the standard metre in terms of the wave-lengths of certain of the cadmium rays, has suggested the adoption of the wave-length of one such ray as a standard with which national standards of length should be compared. Polarization phenomena, and particularly the rotation of the plane of polarization by such substances as sugar solutions, have led to the invention and improvements of polarimeters. The polarized light employed in such instruments is invariably obtained by transmission through a fixed Nicol prism - the polarizer - and the deviation is measured by the rotation of a second Nicol - the analyser. The early forms, which were termed " light and shade " polarimeters, have been generally replaced by " half-shade " instruments. Mention may also be made of the microscopic examination of objects in polarized light, the importance of which as a method of crystallographic and petrological research was suggested by Nicol, developed by Sorby and greatly expanded by Zirkel, Rosenbusch and others.
Bibliography. - There are numerous text-books which give elementary expositions of light and optical phenomena. More advanced works, which deal with the subject experimentally and mathematically, are A. B. Bassett, Treatise on Physical Optics (1892); Thomas Preston, Theory of Light, 2nd ed. by C. F. Joly (1901); R. W. Wood, Physical Optics (1905), which contains expositions on the electromagnetic theory, and treats " dispersion " in great detail. Treatises more particularly theoretical are James Walker, Analytical Theory of Light (1904); A. Schuster, Theory of Optics (1904); P. Drude, Theory of Optics, Eng. trans. by C. R. Mann and R. A. Millikan (1902). General treatises of exceptional merit are A. Winkelmann, Handbuch der Physik, vol. vi. " Optik " (1904); and E. Mascart, Traite d'optique (1889-1893); M. E. Verdet, Lecons d'optique physique (1869, 1872) is also a valuable work. Geometrical optics is treated in R. S. Heath, Geometrical Optics (2nd ed., 1898); H. A. Herman, Treatise on Geometrical Optics (1900). Applied optics, particularly with regard to the theory of optical instruments, is treated in H. D. Taylor, A System of Applied Optics (1906); E. T. Whittaker, The Theory of Optical Instruments (1907); in the publications of the scientific staff of the Zeiss works at Jena: Die Theorie der optischen Instrumente, vol. i. " Die Bilderzeugung in optischen Instrumenten " (1904); in S. Czapski, Theorie der optischen Instrumente, 2nd ed. by 0. Eppenstein (1904); and in A. Steinheil and E. Voit, Handbuch der angewandten Optik (Igo'). The mathematical theory of general optics receives historical and modern treatment in the Encyklopddie der mathematischen Wissenschaften (Leipzig). Meteorological optics is fully treated in J. Pernter, Meteorologische Optik; and physiological optics in H. v. Helmholtz, Handbuch der physiologischen Optik (1896) and in A. Koenig, Gesammelte Abhandlungen zur physiologischen Optik (1903).
The history of the subject may be studied in J. C. Poggendorff, Geschichte der Physik (1879); F. Rosenberger, Die Geschichte der Physik (1882-1890); E. Gerland and F. Traumuller, Geschichte der physikalischen Experimentierkunst (1899); reference may also be. made to Joseph Priestley, History and Present State of Discoveries relating to Vision, Light and Colours (1772), German translation by G. S. Kliigel (Leipzig, 1775). Original memoirs are available in many cases in their author's " collected works," e.g. Huygens, Young, Fresnel, Hamilton, Cauchy, Rowland, Clerk Maxwell, Stokes (and also his Burnett Lectures on Light), Kelvin (and also his Baltimore Lectures, 1904) and Lord Rayleigh. Newton's Opticks forms volumes 96 and 97 of Ostwald's Klassiker; Huygens' Ober d. Licht (1678), vol. 20, and Kepler's Dioptrice (1611), vol. 144 of the same series.
Contemporary progress is reported in current scientific journals, e.g. the Transactions and Proceedings of the Royal Society, and of the Physical Society (London), the Philosophical Magazine (London), the Physical Review (New York, 1893 seq.) and in the British Association Reports; in the Annales de chimie et de physique and Journal de physique (Paris); and in the Physikalische Zeitschrift (Leipzig) and the Annalen der Physik and Chemie (since 1900: Annalen der Physik) (Leipzig). (C. E.*) II. Nature Of Light 1. Newton's Corpuscular Theory. - Until the beginning of the 19th century physicists were divided between two different views concerning the nature of optical phenomena. According to the one, luminous bodies emit extremely small corpuscles which can freely pass through transparent substances and produce the sensation of light by their impact against the retina. This emission or corpuscular theory of light was supported by the authority of Isaac Newton,' and, though it has been entirely superseded by its rival, the wave-theory, it remains of considerable historical interest.
2. Explanation of Reflection and Refraction
Newton supposed the light-corpuscles to be subjected to attractive and repulsive forces exerted at very small distances by the particles of matter. In the interior of a homogeneous body a corpuscle moves in a straight line as it is equally acted on from all sides, but it changes its course at the boundary of two bodies, because, in a thin layer near the surface there is a resultant force in the direction of the normal. In modern language we may say that a corpuscle has at every point a definite potential energy, the value of which is constant throughout the interior of a homogeneous body, and is even equal in all bodies of the same kind, but changes from one substance to another. If, originally, while moving in air, the corpuscles had a definite velocity vo, their velocity v in the interior of any other substance is quite determinate. It is given by the equation 2mv 2 -1mv 0 2 =A, in which m denotes the mass of a corpuscle, and A the excess of its potential energy in air over that in the substance considered.
A ray of light falling on the surface of separation of two bodies is reflected according to the well-known simple law, if the corpuscles are acted on by a sufficiently large force directed towards the first medium. On the contrary, whenever the field of force near the surface is such that the corpuscles can penetrate into the interior of the second body, the ray is refracted. In this case the law of Snellius can be deduced from the consideration that the projection w of the velocity on the surface of separation is not altered, either in direction or in magnitude. This obviously requires that the plane passing through the incident and the refracted rays be normal to the surface, and that, if a, and a 2 are the angles of incidence and of refraction, v, and v 2 the velocities of light in the two media, sin a l /sin a 2 =w/v,.: w/v 2 =v 2 /v i. (I) The ratio is constant, because, as has already been observed, v 1 and v 2 have definite values.
As to the unequal refrangibility of differently coloured light, Newton accounted for it by imagining different kinds of corpuscles. He further carefully examined the phenomenon of total reflection, and described an interesting experiment connected with it. If one of the faces of a glass prism receives on the inside a beam of light of such obliquity that it is totally reflected under ordinary circumstances, 1 Newton, Opticks (London, 1704).
a marked change is observed when a second piece of glass is made to approach the reflecting face, so as to be separated from it only by a very thin layer of air. The reflection is then found no longer to be total, part of the light finding its way into the second piece of glass. Newton concluded from this that the corpuscles are attracted by the glass even at a certain small measurable distance.
3. New Hypotheses in the Corpuscular Theory. - The preceding explanation of reflection and refraction is open to a very serious objection. If the particles in a beam of light all moved with the same velocity and were acted on by the same forces, they all ought to follow exactly the same path. In order to understand that part of the incident light is reflected and part of it transmitted, Newton imagined that each corpuscle undergoes certain alternating changes; he assumed that in some of its different " phases " it is more apt to be reflected, and in others more apt to be transmitted. The same idea was applied by him to the phenomena presented by very thin layers. He had observed that a gradual increase of the thickness of a layer produces periodic changes in the intensity of the reflected light, and he very ingeniously explained these by his theory. It is clear that the intensity of the transmitted light will be a minimum if the corpuscles that have traversed the front surface of the layer, having reached that surface while in their phase of easy transmission, have passed to the opposite phase the moment they arrive at the back surface. As to the nature of the alternating phases, Newton (Opticks, 3rd ed., 1721, p. 347) expresses himself as follows: - " Nothing more is requisite for putting the Rays of Light into Fits of easy Reflexion and easy Transmission than that they be small Bodies which by their attractive Powers, or some other Force, stir up Vibrations in what they act upon, which Vibrations being swifter than the Rays, overtake them successively, and agitate them so as by turns to increase and decrease their Velocities, and thereby put them into those Fits." 4. The Corpuscular Theory and the Wave-Theory compared. - Though Newton introduced the notion of periodic changes, which was to play so prominent a part in the later development of the wave-theory, he rejected this theory in the form in which it had been set forth shortly before by Christiaan Huygens in his TraiU de la lumiere (1690), his chief objections being: (1) that the rectilinear propagation had not been satisfactorily accounted for; (2) that the motions of heavenly bodies show no sign of a resistance due to a medium filling all space; and (3) that Huygens had not sufficiently explained the peculiar properties of the rays produced by the double refraction in Iceland spar. In Newton's days these objections were of much weight.
Yet his own theory had many weaknesses. It explained the propagation in straight lines, but it could assign no cause for the equality of the speed of propagation of all rays. It adapted itself to a large variety of phenomena, even to that of double refraction (Newton says [ibid.]: - ".. . the unusual Refraction of Iceland Crystal looks very much as if it were perform'd by some kind of attractive virtue lodged in certain Sides both of the Rays, and of the Particles of the Crystal."), but it could do so only at the price of losing much of its original simplicity.
In the earlier part of the 19th century, the corpuscular theory broke down under the weight of experimental evidence, and it received the final blow when J. B. L. Foucault proved by direct experiment that the velocity of light in water is not greater than that in air, as it should be according to the formula (1), but less than it, as is required by the wave-theory.
5. General Theorems on Rays of Light
With the aid of suitable assumptions the Newtonian theory can accurately trace the course of a ray of light in any system of isotropic bodies, whether homogeneous or otherwise; the problem being equivalent to that of determining the motion of a material point in a space in which its potential energy is given as a function of the coordinates. The application of the dynamical principles of " least and of varying action " to this latter problem leads to the following important theorems which William Rowan Hamilton made the basis of his exhaustive treatment of systems of rays.' The total energy of a corpuscle is supposed to have 1 Trans. Irish Acad. 15, p. 69 (1824); 16, part 1. " Science," p. 4 (1830), part ii., ibid. p. 93 (1830); 17, part i., p. i (1832).
a given value, so that, since the potential energy is considered as known at every point, the velocity v is so likewise.
(a) The path along which light travels from a point A to a point B is determined by the condition that for this line the integral fvds, in which ds is an element of the line, be a minimum (provided A and B be not too near each other). Therefore, since v=µvo, if vo is the velocity of light in vacuo and u the index of refraction, we have for every variation of the path the points A and B remaining fixed, Sfuds = o. (2) (b) Let the point A be kept fixed, but let B undergo an infinitely small displacement BB' (=q) in a direction making an angle B with the last element of the ray AB. Then, comparing the new ray AB' with the original one, it follows that Sf i ids = µBq cos 6, (3) where AB is the value of j. at the point B.)j, 6. General Considerations on the Propagation of Waves.- " Waves," i.e. local disturbances of equilibrium travelling onward with a certain speed, can exist in a large variety of systems. In a theory of these phenomena, the state of things at a definite point may in general be defined by a certain directed or vector quantity P, 2 which is zero in the state of equilibrium, and may be called the disturbance (for example, the velocity of the air in the case of sound vibrations, or the displacement of the particles of an elastic body from their positions of equilibrium). The components P x, P,,, P E. of the disturbance in the directions of the axes of coordinates are to be considered as functions of the coordinates x, y, z and the time t, determined by a set of partial differential equations, whose form depends on the nature of the problem considered. If the equations are homogeneous and linear, as they always are for sufficiently small disturbances, the following theorems hold.
(a) Values of Pr, P,,, P z (expressed in terms of x, y, z, t) which satisfy the equations will do so still after multiplication by a common arbitrary constant.
(b) Two or more solutions of the equations may be combined into a new solution by addition of the values of Px, those of P,, &c., i.e. by compounding the vectors P, such as they are in each of the particular solutions.
In the application to light, the first proposition means that the phenomena of propagation, reflection, refraction, &c., can be produced in the same way with strong as with weak light. The second proposition contains the principle of the " superposition " of different states, on which the explanation of all phenomena of interference is made to depend.
In the simplest cases (monochromatic 'or homogeneous light) the disturbance is a simple harmonic function of the time (" simple harmonic vibrations "), so that its components can be represented by Px =a, cos (ntd-fi), Py =a. 2 cos (nt - { - f 2), 'P' z =a 3 cos (nt-}-f3). The " phases " of these vibrations are determined by the angles &c., or by the times t+f i /n, &c. The " frequency " n is constant throughout the system, while the quantities fi, f2, f3, and perhaps the " amplitudes " a2, a, change from point to point. It may be shown that the end of a straight line representing the vector P, and drawn from the point considered, in general describes a certain ellipse, which becomes a straight line, if f i =f2 =f3. In this latter case, to which the larger part of this article will be confined, we can write in vector notation P=A cos (ntd-f), (4) where A itself is to be regarded as a vector.
We have next to consider the way in which the disturbance changes from point to point. The most important case is that of plane waves with constant amplitude A. Here f is the same at all points of a plane (" wave-front ") of a definite direction, but changes as a linear function as we pass from one such wave-front to the next. The axis of x being drawn at right angles to the wave-fronts, we may write f =fo - kx, where fo and k are constants, so that (4) becomes P=A cos (nt - kx+fo). (5) This expression has the period 27r/n with respect to the time and the perion 27/k with respect to x, so that the " time of vibration " and the " wave-length " are given by T = 27r/n, X = 27r/k. Further, it is easily seen that the phase belonging to certain values of x and t is equal to that which corresponds to x Ox and t -{- At provided Ax= (n/kW. Therefore the phase, or the disturbance itself, may be said to be propagated in the direction normal to the wave-fronts with a velocity (velocity of the waves) v = n/k, which is connected with the time of vibration and the wave-length by the relation X =vT. (6) This kind of type will always be used in this article to denote vectors.
In isotropic bodies the propagation can go on in all directions with the same velocity. In anisotropic bodies (crystals), with which the theory of light is largely concerned, the problem is more complicated. As a general rule we can say that, for a given direction of the wavefronts, the vibrations must have a determinate direction, if the propagation is to take place according to the simple formula given above. It is to be understood that for a given direction of the waves there may be two or even more directions of vibration of the kind, and that in such a case there are as many different velocities, each belonging to one particular direction of vibration.
7. Wave-surface
After having found the values of v for a particular frequency and different directions of the wavenormal, a very instructive graphical representation can be employed.
Let ON be a line in any direction, drawn from a fixed point 0, OA a length along this line equal to the velocity v of waves having ON for their normal, or, more generally, OA, OA', &e., lengths equal to the velocities v, v', &c., which such waves have according to their direction of vibration, Q, Q', &c., planes perpendicular to ON through A, A, &c. Let this construction be repeated for all directions of ON, and let W be the surface that is touched by all the planes Q, Q', &c. It is clear that if this surface, which is called the " wave-surface," is known, the velocity of propagation of plane waves of any chosen direction is given by the length of the perpendicular from the centre 0 on a tangent plane in the given direction. It must be kept in mind that, in general, each tangent plane corresponds to one definite direction of vibration. If this direction is assigned in each point of the wavesurface, the diagram contains all the information which we can desire concerning the propagation of plane waves of the frequency that has been chosen.
The plane Q employed in the above construction is the position after unit of time of a wave-front perpendicular to ON and originally passing through the point O. The surface W itself is often considered as the locus of all points that are reached in unit of time by a disturbance starting from 0 and spreading towards all sides. Admitting the validity of this view, we can determine in a similar way the locus of the points reached in some infinitely short time dt, the wavesurface, as we may say, or the " elementary wave," corresponding to this time. It is similar to W, all dimensions of the latter surface being multiplied by dt. It may be noticed that in a heterogeneous medium a wave of this kind has the same form as if the properties of matter existing at its centre extended over a finite space.
8. Theory of Huygens. - Huygens was the first to show that the explanation of optical phenomena may be made to depend on the wave-surface, not only in isotropic bodies, in which it has a spherical form, but also in crystals, for one of which (Iceland spar) he deduced the form of the surface from the observed double refraction. In his argument Huygens availed himself of the following principle that is justly named after him: Any point that is reached by a wave of light becomes a new centre of radiation from which the disturbance is propagated towards all sides. On this basis he determined the progress of light-waves by a construction which, under a restriction to be mentioned in §13, applied to waves of any form and to all kinds of transparent media. Let obe the surface (wave-front) to which a definite phase of vibration has advanced at a certain time t, dt an infinitely small increment of time, and let an elementary wave corresponding to this interval be described around each point P of a. Then the envelope v' of all these elementary waves is the surface reached by the phase in question at the time t+dt, and by repeating the construction all successive positions of the wave-front can be found.
Huygens also considered the propagation of waves that are laterally limited, by having passed, for example, through an opening in an opaque screen. If, in the first wave-front a, the disturbance exists only in a certain part bounded by the contour s, we can confine ourselves to the elementary waves around the points of that part, and to a portion of the new wave-front a' whose boundary passes through the points where a' touches the elementary waves having their centres on s. Taking for granted Huygens's assumption that a sensible disturbance is only found in those places where the elementary waves are touched by the new wave-front, it may be inferred that the lateral limits of the beam of light are determined by lines, each element of which joins the centre P of an elementary wave with its point of contact P' with the next wave-front. To lines of this kind, whose course can be made visible by using narrow pencils of light, the name of " rays " is to be given in the wave-theory. The disturbance may be conceived to travel along them with a velocity u = PP'/dt, which is therefore called the " ray-velocity." The construction shows that, corresponding to each direction of the wave-front (with a determinate direction of vibration), there is a definite direction and a definite velocity of the ray. Both are given (cf. equation t).
9. General Theorems on Rays, deduced from Huygens's Construction.
(a) Let A and B be two points arbitrarily chosen in a system of transparent bodies, ds an element of a line drawn from A to B, u the velocity of a ray of light coinciding with ds. Then the integral fu l ds, which represents the time required for a motion along the line with the velocity u, is a minimum for the course actually taken by a ray of light (unless A and B be too far apart). This is the " principle of least time " first formulated by Pierre de Fermat for the case of two isotropic substances. It shows that the course of a ray of light can always be inverted.
(b) Rays of light starting in all directions from a point A and travelling onward for a definite length of time, reach a surface a, whose tangent plane at a point B is conjugate, in the medium surrounding B, with the last element of the ray AB.
(c) If all rays issuing from A are concentrated at a point B, the integral fu 'ds has the same value for each of them.
(d) In case (b) the variation of the integral caused by an infinitely small displacement q of B, the point A remaining fixed, is given by Sfu l ds=q cos 0/v B . Here 0 is the angle between the displacement q and the normal to the surface a, in the direction of propagation, vs the velocity of a plane wave tangent to this surface.
In the case of isotropic bodies, for which the relation (8) holds, we recover the theorems concerning the integral feeds which we have deduced from the emission theory (§ 5).
10. Further General Theorems. - (a) Let V 1 and be two planes in a system of isotropic bodies, let rectangular axes of coordinates be chosen in each of these planes, and let x i , y1 be the coordinates of a point A in V 1, and those of a point B in The integral fads, taken for the ray between A and B, is a function of x 1 , and, if 51 denotes either x 1 ory l, and 12 either x 2 or y 21 we shall have as = a1 a f Ads. On both sides of this equation the first differentiation may be performed by means of the formula (3). The second differentiation admits of a geometrical interpretation, and the formula may finally be employed for proving the following theorem: Let w l be the solid angle of an infinitely thin pencil of rays issuing from A and intersecting the plane in an element a 2 at the point B. Similarly, let w 2 be the solid angle of a pencil starting from B and falling on the element a l of the plane V 1 at the point A. Then, denoting by 111 and 112 the indices of refraction of the matter at the points A and B, by 01 and 0 2 the sharp angles which the ray AB at its extremities makes with the normals to V1 and V2, we have 1 1 1 a 1 = 1122 a 2 w 2 cos (b) There is a second theorem that is expressed by exactly the same formula, if we understand by a l and a 2 elements of surface that are related to each other as an object and its optical image - by col, w2 the infinitely small openings, at the beginning and the end of its course, of a pencil of rays issuing from a point A of a i and coming together at the corresponding point B of a 2, and by 0 1, the sharp angles which one of the rays makes with the normals to a l and a2. The proof may be based upon the first theorem. It suffices to by a line drawn from the centre of the wave-surface to its point of contact with a tangent plane of the given direction. It will be convenient to say that this line and the plane are conjugate with each other. The rays of light, curved in non-homogeneous bodies, are always straight lines in homogeneous substances. In an isotropic medium, whether homogeneous or otherwise, they are normal to the wave-fronts, and their velocity is equal to that of the waves.
By applying his construction to the reflection and refraction of light, Huygens accounted for these phenomena in isotropic bodies as well as in Iceland spar. rt was afterwards shown by Augustin Fresnel that the double refraction in biaxal crystals can be explained in the same way, provided the proper form be assigned to the wavesurface.
In any point of a bounding surface the normals to the reflected and refracted waves, whatever be their number,. always lie in the plane passing through the normal to the incident waves and that to the surface itself. Moreover, if a l is the angle between these two latter normals, and a 2 the angle between the normal to the boundary and that to any one of the reflected and refracted waves, and v,, v 2 the corresponding wave-velocities, the relation sin a l /sin a 2 = v1/v2 (7) is found to hold in all cases. These important theorems may be proved independently of Huygens's construction by simply observing that, at each point of the surface of separation, there must be a certain connexion between the disturbances existing in the incident, the reflected, and the refracted waves, and that, therefore, the lines of intersection of the surface with the positions of an incident wavefront, succeeding each other at equal intervals of time dt, must coincide with the lines in which the surface is intersected by a similar series of reflected or refracted wave-fronts.
In the case of isotropic media, the ratio (7) is constant, so that we are led to the law of Snellius, the index of refraction being given by (8) consider the section a of the pencil by some intermediate plane, and a bundle of rays starting from the points of a l and reaching those of a 2 after having all passed through a point of that section o-. (c) If in the last theorem the system of bodies is symmetrical around the straight line AB, we can take for a l and 6r 2 circular planes having AB as axis. Let h l and h 2 be the radii of these circles, i.e. the linear dimensions of an object and its image, ei and e2 the infinitely small angles which a ray R going from A to B makes with the axis at these points. Then the above formula gives / 1,h l e i =A2h2e2, a relation that was proved, for the particular case =P2 by Huygens and Lagrange. It is still more valuable if one distinguishes by the algebraic sign of h 2 whether the image is direct or inverted, and by that of e 2 whether the ray R on leaving A and on reaching B lies on opposite sides of the axis or on the same side.
The above theorems are of much service in the theory of optical instruments and in the general theory of radiation.
II. Phenomena of Interference and Diffraction. - The impulses or motions which a luminous body sends forth through the universal medium or aether, were considered by Huygens as being without any regular succession; he neither speaks of vibrations, nor of the physical cause of the colours. The idea that monochromatic light consists of a succession of simple harmonic vibrations like those represented by the equation (5), and that the sensation of colour depends on the frequency, is due to Thomas Young' and Fresnel, 2 who explained the phenomena of interference on this assumption combined with the principle of super-position. In doing so they were also enabled to determine the wave-length, ranging from o000076 cm. at the red end of the spectrum to o000039 cm. for the extreme violet and, by means of the formula (6), the number of vibrations per second. Later investigations have shown that the infra-red rays as well as the ultra-violet ones are of the same physical nature as the luminous rays, differing from these only by the greater or smaller length of their waves. The wave-length amounts to 0o06 cm. for the least refrangible infra-red, and is as small as o00001 cm. for the extreme ultraviolet.
Another important part of Fresnel's work is his treatment of diffraction on the basis of Huygens's principle. If, for example, light falls on a screen with a narrow slit, each point of the slit is regarded as a new centre of vibration, and the intensity at any point behind the screen is found by compounding with each other the disturbances coming from all these points, due account being taken of the phases with which they come together (see Diffraction; Interference).
i 2. Results of Later Mathematical Theory. - Though the theory of diffraction developed by Fresnel, and by other physicists who worked on the same lines, shows a most beautiful agreement with observed facts, yet its foundation, Huygens's principle, cannot, in its original elementary form, be deemed quite satisfactory. The general validity of the results has, however, been confirmed by the researches of those mathematicians (Simeon Denis Poisson, Augustin Louis Cauchy, Sir G. G. Stokes, Gustav Robert Kirchhoff) who investigated the propagation of vibrations in a more rigorous manner. Kirchhoff 3 showed that the disturbance at any point of the aether inside a closed surface which contains no ponderable matter can be represented as made up of a large number of parts, each of which depends upon the state of things at one point of the surface. This result, the modern form of Huygens's principle, can be extended to a system of bodies of any kind, the only restriction being that the source of light be not surrounded by the surface. Certain causes capable of producing vibrations can be imagined to be distributed all over this latter, in such a way that the disturbances to which they give rise in the enclosed space are exactly those which are brought about by the real source of light. 4 Another interesting result that has been verified by experiment is that, whenever rays of light pass through a focus, the phase undergoes a change of half a period. It must be added that the results alluded to in 1 Phil. Trans. (1802), part i. p. 12.
Ouvres completes de Fresnel (Paris, 1866). (The researches were published between 1815 and 1827.) Ann. Phys. Chem. (1883), 18, p. 663.
4 H. A. Lorentz, Zittingsversl. Akad. v. Wet. Amsterdam, 4 (1896), p. 176.
the above, though generally presented in the terms of some particular form of the wave theory, often apply to other forms as well.
13. Rays of Light
In working out the theory of diffraction it is possible to state exactly in what sense light may be said to travel in straight lines. Behind an opening whose width is very large in comparison with the wave-length the limits between the illuminated and the dark parts of space are approximately determined by rays passing along the borders.
This conclusion can also be arrived at by a mode of reasoning that is independent of the theory of diffraction.' If linear differential equations admit a solution of the form (5) with A constant, they can also be satisfied by making A a function of the coordinates, such that, in a wave-front, it changes very little over a distance equal to the wave-length X, and that it is constant along each line conjugate with the wave-fronts. In cases of this kind the disturbance may truly be said to travel along lines of the said direction, and an observer who is unable to discern lengths of the order of X, and who uses an opening of much larger dimensions, may very well have the impression of a cylindrical beam with a sharp boundary.
A similar result is found for curved waves. If the additional restriction is made that their radii of curvature be very much larger than the wave-length, Huygens's construction may confidently be employed. The amplitudes all along a ray are determined by, and proportional to, the amplitude at one of its points.
14. Polarized Light
As the theorems used in the explanation of interference and diffraction are true for all kinds of vibratory motions, these phenomena can give us no clue to the special kind of vibrations in light-waves. Further information, however, may be drawn from experiments on plane polarized light. The properties of a beam of this kind are completely known when the position of a certain plane passing through the direction of the rays, and in which the beam is said to be polarized, is given. " This plane of polarization," as it is called, coincides with the plane of incidence in those cases where the light has been polarized by reflection on a glass surface under an angle of incidence whose tangent is equal to the index of refraction (Brewster's law).
The researches of Fresnel and Arago left no doubt as to the direction of the vibrations in polarized light with respect to that of the rays themselves. In isotropic bodies at least, the vibrations are exactly transverse, i.e. perpendicular to the rays, either in the plane of polarization or at right angles to it. The first part of this statement also applies to unpolarized light, as this can always be dissolved into polarized components.
Much experimental work has been done on the production of polarized rays by double refraction and on the reflection of polarized light, either by isotropic or by anisotropic transparent bodies, the object of inquiry being in the latter case to determine the position of the plane of polarization of the reflected rays and their intensity.
In this way a large amount of evidence has been gathered by which it has been possible to test different theories concerning the nature of light and that of the medium through which it is propagated. A common feature of nearly all these theories is that the aether is supposed to exist not only in spaces void r of matter, but also in the interior of ponderable bodies.
15. Fresnel's Theory. - Fresnel and his immediate successors assimilated the aether to an elastic solid, so that the velocity of propagation of transverse vibrations could be determined by the formula v=,J(K/p), where K denotes the modulus of rigidity and p the density. According to this equation the different properties of various isotropic transparent bodies may arise from different values of K, of p, or of both. It has, however, been found that if both K and p are supposed to change from one substance to another, it is impossible to obtain the right reflection formulae. Assuming the constancy of K Fresnel was led to equations which agreed with the observed properties of the reflected light, if he made the further assumption (to be mentioned in what follows as " Fresnel's assumption ") that the vibrations of plane polarized light are perpendicular to the plane of polarization.
5 H. A. Lorentz, Abhandlungen fiber theoretische Physik, 1 (1907), P. 415.
an= tan (al - a2)/ tan (al-}-a2) (to) in the second principal case.
As to double refraction, Fresnel made it depend on the unequal elasticity of the aether in different directions. He came to the conclusion that, for a given direction of the waves, there are two possible directions of vibration (§ 6), lying in the wave-front, at right angles to each other, and he determined the form of the wave-surface, both in uniaxal and in biaxal crystals.
Though objections may be urged against the dynamic part of Fresnel's theory, he admirably succeeded in adapting it to the facts.
16. Electromagnetic Theory. - We here leave the historical order and pass on to Maxwell's theory of light.
James Clerk Maxwell, who had set himself the task of mathematically working out Michael Faraday's views, and who, both by doing so and by introducing many new ideas of his own, became the founder of the modern science of electricity,' recognized that, at every point of an electromagnetic field, the state of things can be defined by two vector quantities, the " electric force " E and the " magnetic force " H, the former of which is the force acting on unit of electricity and the latter that which acts on a magnetic pole of unit strength. In a non-conductor (dielectric) the force E produces a state that may be described as a displacement of electricity from its position of equilibrium. This state is represented by a vector D (" dielectric displacement ") whose magnitude is measured by the quantity of electricity reckoned per unit area which has traversed an element of surface perpendicular to D itself. Similarly, there is a vector quantity B (the " magnetic induction ") intimately connected with the magnetic force H. Changes of the dielectric displacement constitute an electric current measured by the rate of change of D, and represented in vector notation by C==D (II) Periodic changes of D and B may be called " electric " and " magnetic vibrations." Properly choosing the units, the axes of coordinates (in the first proposition also the positive direction of s and n), and denoting components of vectors by suitable indices, we can express in the following way the fundamental propositions of the theory.
(a) Let s be a closed line, a a surface bounded by it, n the normal to a. Then, for all bodies, H 8 ds = f C n dcr, J Esds = - d f Bnda, where the constant c means the ratio between the electro-magnet and the electrostatic unit of electricity.
From these equations we can deduce: (a) For the interior of a body, the equations aHz _ aH _ 1 aHz _ 8H z _ t aH _ aH x t () ay az C z, a x = C5, ax -- a y = cCz 12 aE z 3Ey aB aE aB _ 1 x aE x z 1 y 3E, aE x _ 1 3Bz ay - az - - c at' az c a t ' ax - ay - c ' at ' (13) (0) For a surface of separation, the continuity of the tangential components of E and H; (y) The solenoidal distribution of C and B, and in a dielectric that of D. A solenoidal distribution of a vector is one corresponding to that of the velocity in an incompressible fluid. It involves the continuity, at a surface, of the normal component of the vector.
(b) The relation between the electric force and the dielectric displacement is expressed by Dx = eiEx, Dy = e2Ey, D z = E3Ez, (14) the constants (dielectric constants) depending on the properties of the body considered. In an isotropic medium they have a common value e, which is equal to unity for the free aether, so that for this medium D = E.
(c) There is a relation similar to (14) between the magnetic force and the magnetic induction. For the aether, however, and for all ponderable bodies with which this article is concerned, we may write B =H.
It follows from these principles that, in an isotropic dialectric, transverse electric vibrations can be propagated with a velocity v = c/-J E. (15) Indeed, all conditions are satisfied if we put Dx =o, Dy =a cos n(t - xtr'+l), 'D z =o, H z =o, H y =0, Hz= avc 1 cos n(t - xa+l) (16) For the free aether the velocity has the value c. Now it had been found that the ratio c between the two units of electricity agrees within the limits of experimental errors with the numerical value of the velocity of light in aether. (The mean result of the most exact determinations 2 of c is 3,001to 10 cm./sec., the largest deviations being about 0,00810 10 :. and Cornu 3 gives 3,001to 10 o,003t010 as the most probable value of the velocity of light.) By this Maxwell was led to suppose that light consists of transverse electromagnetic disturbances. On this assumption, the equations (16) represent a beam of plane polarized light. They show that, in such a beam, there are at the same time electric and magnetic vibrations, both transverse, and at right angles to each other.
It must be added that the electromagnetic field is the seat of two kinds of energy distinguished by the names of electric and magnetic energy, and that, according to a beautiful theorem due to J. H. Poynting, 4 the energy may be conceived to flow in a direction perpendicular both to the electric and to the magnetic force. The amounts per unit of volume of the electric and the magnetic energy are given by the expressions 2 (+ E y D y+ E z D z), (17) a(HxBx +Hy B y+HzBz) = (18) whose mean values for a full period are equal in every beam of light.
The formula (15) shows that the index of refraction of a body is given by A(a result that has been verified by Ludwig Boltzmann's measurements' of the dielectric constants of gases. Thus Maxwell's theory can assign the true cause of the different optical properties of various transparent bodies. It also leads to the reflection formulae (9) and (to), provided the electric vibrations of polarized light be supposed to be perpendicular to the plane of polarization, which implies that the magnetic vibrations are parallel to that plane.
Following the same assumption Maxwell deduced the laws of double refraction, which he ascribes to the unequality of E l, 21 His results agree with those of Fresnel and the theory has been confirmed by Boltzmann,' who measured the three coefficients in the case of crystallized sulphur, and compared them with the principal indices of refraction. Subsequently the problem of crystalline reflection has been completely solved and it has been shown that, in a crystal, Poynting's flow of energy has the direction of the rays as determined by Huygens's construction.
Two further verifications must here be mentioned. In the first place, though we shall speak almost exclusively of the propagation of light in transparent dielectrics, a few words may be said about the optical properties of conductors. The simplest assumption concerning the electric current C in a metallic body is expressed by the equation C = QE, where a is the coefficient of conductivity. Combining this with his other formulae (we may say with (12) and (13)), Maxwell found that there must be an absorption of light, a result that can be readily understood since the motion of electricity in a conductor gives rise to a development of heat. But, though Maxwell accounted in this way for the fundamental fact that metals are opaque bodies, there remained a wide divergence between the values of the coefficient of absorption as directly measured and as calculated from the electrical conductivity; but in 1903 it was shown by E. Hagen and H. Rubens 7 that the agreement is very satisfactory in the case of the extreme infra-red rays.
In the second place, the electromagnetic theory requires that a surface struck by a beam of light shall experience a certain pressure. If the beam falls normally on a plane disk, the pressure is normal too; its total amount is given by c-1(ii-{-12 - 13), if i l, i 2 and i 3 are the quantities of energy that are carried forward per unit of time by the incident, the reflected, and the transmitted light. This result has been quantitatively verified by E. F. Nicholls and G. F. Hull.' Maxwell's predictions have been splendidly confirmed by the experiments of Heinrich Hertz' and others on electromagnetic waves; by diminishing the length of these to the utmost, some physicists have been able to reproduce with them all phenomena of reflection, refraction (single and double), interference, and polarization. 10 A table of the wave-lengths observed in the aether now has Let the indices p and n relate to the two principal cases in which the incident (and, consequently, the reflected) light is polarized in the plane of incidence, or normally to it, and let positive directions h and h be chosen for the disturbance (at the surface itself) in the incident and for that in the reflected beam, in such a manner that, by a common rotation, h and the incident ray prolonged may be made to coincide with h and the reflected ray. Then, if a l and a2 are the angles of incidence and refraction, Fresnel shows that, in order to get the reflected disturbance, the incident one must be multiplied by ap= - sin (a l - a 2)/ sin (al+a2) (9) ' Clerk Maxwell, A Treatise on Electricity and Magnetism (Oxford, 1st ed., 1873).
and 2 H. Abraham, Rapports presentes au congres de physique de 7900 (Paris), 2, P. 247. Ibid., p. 225.
4 Phil. Trans., 1 75 (1884), P. 3435 Ann. d. Phys. u. Chem. 1 55 (1875), p. 403.
s Ibid. 1 53 (1874), p. 525.
7 Ann. d. Phys. (1903), p. 873.
Phys. Review, 13 (1901), p. 293.
Hertz, Untersuchungen fiber die Ausbreitung der elektrischen Kraft (Leipzig, 1892).
i° A. Righi, L'Ottica delle oscillazioni elettriche (Bologna, 18 97); P. Lebedew, Ann. d. Phys. u. Chem., 56 (1895), p. 1.
to contain, besides the numbers given in § 22, the lengths of the waves produced by electromagnetic apparatus and extending from the long waves used in wireless telegraphy down to about o6 cm.
i 7. Mechanical Models of the Electromagnetic Medium. - From the results already enumerated, a clear idea can be formed of the difficulties which were encountered in the older form of the wave-theory. Whereas, in Maxwell's theory, longitudinal vibrations are excluded ab initio by the solenoidal distribution of the electric current, the elastic-solid theory had to take them into account, unless, as was often done, one made them disappear by supposing them to have a very great velocity of propagation, so that the aether was considered to be practically incompressible. Even on this assumption, however, much in Fresnel's theory remained questionable. Thus George Green,' who was the first to apply the theory of elasticity in an unobjectionable manner, arrived on Fresnel's assumption at a formula for the reflection coefficient A n sensibly differing from (10).
In the theory of double refraction the difficulties are no less serious. As a general rule there are in an anisotropic elastic solid three possible directions of vibration (§ 6), at right angles to each other, for a given direction of the waves, but none of these lies in the wave-front. In order to make two of them do so and to find Fresnel's form for the wave-surface, new hypotheses are required. On Fresnel's assumption it is even necessary, as was observed by Green, to suppose that in the absence of all vibrations there is already a certain state of pressure in the medium.
If we adhere to Fresnel's assumption, it is indeed scarcely possible to construct an elastic model of the electromagnetic medium. It may be done, however, if the velocities of the particles in the model arc taken to represent the magnetic force H, which, of course, implies that the vibrations of the particles are parallel to the plane of polarization, and that the magnetic energy is represented by the kinetic energy in the model. Considering further that, in the case of two bodies connected with each other, there is continuity of H in the electromagnetic system, and continuity of the velocity of the particles in the model, it becomes clear that the representation of H by that velocity must be on the same scale in all substances, so that, if E, n, I are the displacements of a particle and g a universal constant, we may write Hx =gol, Hy - g ot ' Hz=gat. (29) By this the magnetic energy per unit of volume becomes zg2? (OE) 2 (mi) 2 and since this must be the kinetic energy of the elastic medium, the density of the latter must be taken equal to g 2, so that it must be the same in all substances.
It may further be asked what value we have to assign to the potential energy in the model, which must correspond to the electric energy in the electromagnetic field. Now, on account of (i 2) and 19), we can satisfy the equations (22) by putting Dx' =gc (-), &c., so that the electric energy (17) per unit of volume becomes a?- an aE ag2 I an a ay - z (ax - ay) This, therefore, must be the potential energy in the model.
It may be shown, indeed, that, if the aether has a uniform constant density, and is so constituted that in any system, whether homogeneous or not, its potential energy per unit of volume can be represented by an expression of the form 1 (9,9-1; - '9021-z)2 aE a? 2 an 8E L +M (az - ax) +N (ax - ay) (20) where L, M, N are coefficients depending on the physical properties of the substance considered, the equations of motion will exactly correspond to the equations of the electromagnetic field.
18. Theories of MacCullagh. - A theory of light in which the elastic aether has a uniform density, and in which the vibrations are supposed to be parallel to the plane of polarization, was developed by Franz Ernst Neumann, 2 who gave the first deduction of the formulas for crystalline reflection. Like Fresnel, he was, however, obliged to introduce some illegitimate assumptions and simplifications. Here again Green indicated a more rigorous treatment.
1 " Reflection and Refraction," Trans. Cambr. Phil. Soc. 7, p. I (2837); " Double Refraction," ibid. p. 121 (1839).
Double Refraction," Ann. d. Phys. u. Chem. 25 (1832), p. 428; " Crystalline Reflection," Abhandl. Akad. Berlin (2835), p. I.
By specializing the formula for the potential energy of an anisotropic body he arrives at an expression which, if some of his coefficients are made to vanish and if the medium is supposed to be incompressible, differs from (20) only by the additional terms 2 L a ?- ann-2n a? -{-M aE a? - aa -{-N an a - aE an (22) in 83. ay az (az ax az ax) ax ayax ay) If E, n, ?- vanish at infinite distance the integral of this expression over all space is zero, when L, M, N are constants, and the same will be true when these coefficients change from point to point, provided we add to (22) certain terms containing the differential coefficients of L, M, N, the physical meaning of these terms being that, besides the ordinary elastic forces, there is some extraneous force (called into play by the displacement) acting on all those elements of volume where L, M, N are not constant. We may conclude from this that all phenomena can be explained if we admit the existence of this latter force, which, in the case of two contingent bodies, reduces to a surface-action on their common boundary.
James MacCullagh 3 avoided this complication by simply assuming an expression of the form (20) for the potential energy. He thus established a theory that is perfectly consistent in itself, and may be said to have foreshadowed the electromagnetic theory as regards the form of the equations for transparent bodies. Lord Kelvin afterwards interpreted MacCullagh's assumption by supposing the only action which is called forth by a displacement to consist in certain couples acting on the elements of volume and proportional to the components If (8/3y) - (an/az) }, &c., of their rotation from the natural position. He also showed 4 that this " rotational elasticity " can be produced by certain hidden rotations going on in the medium.
We cannot dwell here upon other models that have been proposed, and most of which are of rather limited applicability. A mechanism of a more general kind ought, of course, to be adapted to what is known of the molecular constitution of bodies, and to the highly probable assumption of the perfect permeability for the aether of all ponderable matter, an assumption by which it has been possible to escape from one of the objections raised by Newton (§ 4) (see Aether).
The possibility of a truly satisfactory model certainly cannot be denied. But it would, in all probability, be extremely complicated. For this reason many physicists rest content, as regards the free aether, with some such general form of the electromagnetic theory as has been sketched in § 16.
19. Optical Properties of Ponderable Bodies. Theory of Electrons. - If we want to form an: adequate representation of optical phenomena in ponderable bodies, the conceptions of the molecular and atomistic theories naturally suggest themselves. Already, in the elastic theory, it had been imagined that certain material particles are set vibrating by incident waves of light. These particles had been supposed to be acted on by an elastic force by which they are drawn back towards their positions of equilibrium, so that they can perform free vibrations of their own, and by a resistance that can be represented by terms proportional to the velocity in the equations of motion, and may be physically understood if the vibrations are supposed to be converted in one way or another into a disorderly heat-motion. In this way it had been found possible to explain the phenomena of dispersion and (selective) absorption, and the connexion between them (anomalous dispersion). 5 These ideas have, been also embodied into the electromagnetic theory. In its more recent development the extremely small, electrically charged particles, to which the name of " electrons " has been given, and which are supposed to exist in the interior of all bodies, are considered as forming the connecting links between aether and matter, and as determining by their arrangement and their motion all optical phenomena that are not confined to the free aether.6 It has thus become clear why the relations that had been established between optical and electrical properties have been found to hold only in some simple cases (§26). In fact it cannot be doubted that, for rapidly alternating electric fields, the formulae expressing the connexion between the motion of electricity and the electric force take a form that is less simple than the one previously admitted, and is to be determined in each case by 3 Trans. Irish Acad. 21, " Science," p. 17 (2839).
4 Math. and Phys. Papers (London, 2890), 3, p. 466.
5 Helmholtz, Ann. d. Phys. u. Chem., 2 54 (2875), p. 582.
6 H. A. Lorentz, Versuch einer Theorie der elektrischen u. optischen Erscheinungen in bewegten Korpern (2895) (Leipzig, 1906); J. Larmor, Aether and Matter (Cambridge, 1900).
elaborate investigation. However, the general boundary conditions given in § 16 seem to require no alteration. For this reason it has been possible, for example, to establish a satisfactory theory of metallic reflection, though the propagation of light in the interior of a metal is only imperfectly understood.
One of the fundamental propositions of the theory of electrons is that an electron becomes a centre of radiation whenever its velocity changes either in direction or in magnitude. Thus the production of Röntgen rays, regarded as consisting of very short and irregular electromagnetic impulses, is traced to the impacts of the electrons of the cathode-rays against the anticathode, and the lines of an emission spectrum indicate the existence in the radiating body of as many kinds of regular vibrations, the knowledge of which is the ultimate object of our investigations about the structure of the spectra. The shifting of the lines caused, according to Doppler's law, by a motion of the source of light, may easily be accounted for, as only general principles are involved in the explanation. To a certain extent we can also elucidate the changes in the emission that are observed when the radiating source is exposed to external magnetic forces (" Zeeman-effect "; see Magnetooptics) .
20. Various Kinds of Light-motion. - (a) If the disturbance is represented by P z = o, P, = a cos (nt - kx+f), 'P Z = a'cos (nt - +f), so that the end of the vector P describes an ellipse in a plane perpendicular to the direction of propagation, the light is said to be elliptically, or in special cases circularly, polarized. Light of this kind can be dissolved in many different ways into plane polarized components.
There are cases in which plane waves must be elliptically or circularly polarized in order to show the simple propagation of phase that is expressed by formulae like (5). Instances of this kind occur in bodies having the property of rotating the plane of polarization, either on account of their constitution, or under the influence of a magnetic field. For a given direction of the wave-front there are in general two kinds of elliptic vibrations, each having a definite form, orientation, and direction of motion, and a determinate velocity of propagation. All that has been said about Huygens's construction applies to these cases.
(b) In a perfect spectroscope a sharp line would only be observed if an endless regular succession of simple harmonic vibrations were admitted into the instrument. In any other case the light will occupy a certain extent in the spectrum, and in order to determine its distribution we have to decompose into simple harmonic functions of the time the components of the disturbance, at a point of the slit for instance. This may be done by means of Fourier's theorem.
An extreme case is that of the unpolarized light emitted by incandescent solid bodies, consisting of disturbances whose variations are highly irregular, and giving a continuous spectrum. But even with what is commonly called homogeneous light, no perfectly sharp line will be seen. There is no source of light in which the vibrations of the particles remain for ever undisturbed, and a particle will never emit an endless succession of uninterrupted vibrations, but at best a series of vibrations whose form, phase and intensity are changed at irregular intervals. The result must be a broadening of the spectral line.
In cases of this kind one must distinguish between the velocity of propagation of the phase of regular vibrations and the velocity with which the said changes travel onward (see below, iii. Velocity of Light). (c) In a train of plane waves of definite frequency the disturbance is represented by means of goniometric functions of the time and the coordinates. Since the fundamental equations are linear, there are also solutions in which one or more of the coordinates occur in an exponential function. These solutions are of interest because the motions corresponding to them are widely different from those of which we have thus far spoken. If, for example, the formulae contain the factor e - zcos (nt - sy +1) with the positive constant r, the disturbance is no longer periodic with respect to x, but steadily diminishes as x increases. A state of things of this kind, in which the vibrations rapidly die away as we leave the surface, exists in the air adjacent to the face of a glass prism by which a beam of light is totally reflected. It furnishes us an explanation of Newton's experiment mentioned in § 2.
(H. A. L.) Velocity Of Light The fact that light is propagated with a definite speed was first brought out by Ole Roemer at Paris, in 1676, through observations of the eclipses of Jupiter's satellites, made in different relative positions of the Earth and Jupiter in their respective orbits. It is possible in this way to determine the time required for light to pass across the orbit of the earth. The dimensions of this orbit, or the distance of the sun, being taken as known, the actual speed of light could be computed. Since this computation requires a knowledge of the sun's distance, which has not yet been acquired with certainty, the actual speed is now determined by experiments made on the earth's surface. Were it possible by any system of signals to compare with absolute precision the times at two different stations, the speed could be determined by finding how long was required for light to pass from one station to another at the greatest visible distance. But this is impracticable, because no natural agent is under our control by which a signal could be communicated with a greater velocity than that of light. It is therefore necessary to reflect a ray back to the point of observation and to determine the time which the light requires to go and come. Two systems have been devised for this purpose. One is that of Fizeau, in which the vital appliance is a rapidly revolving toothed wheel; the other is that of Foucault, in which the corresponding appliance is a mirror revolving on an axis in, or parallel to, its own plane.
The principle underlying Fizeau's method is shown in the accompanying figs. I and 2. Fig. I shows the course of a ray of light which, emanating from a luminous point L, strikes the plane surface of a plate of glass M at an angle of about 45°A fraction of the light is reflected from the two surfaces of the glass to a distant reflector R, the plane of which is at right angles to the course of the ray. The latter is thus reflected back on its own course and, passing through the glass M on its return, reaches a point E behind the glass. An observer with his eye at E iooking through the glass sees the return ray as a distant luminous point in the reflector R, after the Nam light has passed over the course in both directions.
In actual practice it is necessary to interpose the object glass of a telescope at a point 0, at a dis FIG. I.
tance from M nearly equal to its focal length. The function of this appliance is to render the diverging rays, shown by the dotted lines, nearly parallel, in order that more light may reach R and be thrown back again. But the principle may be conceived without respect to the telescope, all the rays being ignored except the central one, which passes over the course we have described.
Conceiving the apparatus arranged in such a way that the observer sees the light reflected from the distant mirror R, a fine toothed wheel WX is placed immediately in front of the glass M, with its plane perpendicular to the course of the ray, in such a way that the ray goes out and returns through an opening between two adjacent teeth. This wheel is represented in section by WX in fig. I, and a part of its circumference, with the teeth as viewed by the observer, is shown in fig. 2. We conceive that the latter sees the luminous point between two of the teeth at K. Now, conceive that the wheel is set in revolution. The ray is then interrupted as every tooth passes, so that what is sent out is a succession of flashes. Conceive that the speed of the mirror is such that while the flash is going to the distant mirror and returning again, each tooth of the wheel takes the place of an opening between the teeth. Then each flash sent out will, on its return, be intercepted by the adjacent tooth, and will therefore become invisible. If the speed be now doubled, so that the teeth pass at intervals equal to the time required for the light to go and come, each flash sent through an opening will return through the adjacent opening, and will therefore be seen with full brightness. If the speed be continuously increased the result will be successive disappearances and reappearances of the light, according as a tooth is or is not interposed when the ray reaches the apparatus on its return. The computation of the time of passage and return is then very simple. The speed of the wheel being known, the number of teeth passing in one second can be computed. The order of the disappearance, or the number of teeth which have passed while the light is going and coming, being also determined in each case, the interval of time is computed by a simple formula.